Great question – you are a budding scientist. I have no idea, i would probably guess it was to do with the fat content. I usually eat them before I get a chance to test this.
This is due to the types of fat these in goodies. For cakes liquid fat is incorporated making it initially softer. However at the cake ages water evaporates making it hard.
For biscuits the inverse is true. They contain solid fat making them initially hard. So they take on water from the atmosphere making them soft. So biscuits don’t go soft in the desert.
This why a jaffa cake is a cake and not a biscuit. Because it is soft to intially and goes hard when stale.
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