Its all to do with surface tension and surface area. A bubble always tries to take up the smallest amount of space and hold the most air that it possibly can. And because a sphere has the lowest possible surface area of any shape it will always form that shape.
You can compare it to a balloon, when you blow up the balloon gas inside the balloon forces equal pressure in all directions forming a round shape, unless of course you have a funny shape balloon, but that’s another story.
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